| 系統識別號 | 27864 | | 篇 名 | 過渡金屬催化的1,6-烯炔環異構化反應 | | 並列篇名 | Cycloisomerization of 1, 6-Enynes Catalyzed by Transition Metals | | 作 者 | 童曉峰(Xiao-Feng Tong);張兆國(Zhao-Guo Zhang) | | 刊 名 | 有機化學 | | 卷期／出版年月 | 24卷6期(2004/06) | | 頁次 | 591-599 | | 資料語文 | 中文 | | 摘要 | 1,6-烯炔底物在過渡金屬催化劑作用下的化學行為得到了廣泛的研究，重點是關於過渡金屬催化的1,6-烯炔環異構化反應，從反應機理角度入手，把1,6-烯炔環異構化反應按啟動方式總結為三類，關對這三種方式啟動的1,6-烯炔構化應進行了詳細地總結和闡述。 The behavior of 1,6-enyne in the presence of transition metal catalysts had been extensively studied . 1,6-Enyne cycloisomerization reactions catalyzed by transition metals and three different reaction pathways, namely cyclometalation, halorhodation and π-allyl rhodium route, divided according to the reaction mechanism are summarized and discussed. | | 關鍵詞 | 1,6-烯炔,過渡金屬,催化,環異構化反應;1,6-enyne,transition metal,catalysis,cycloisomerization | | CEPS分類 | 學科別>自然科學>化學 |
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